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Researching and Writing

PUBLICATIONS

2016 - current

                                                             - INDEPENDENT WORKS AT SNU -

                                                                                                             Coming soon!

                                                             - POSTDOCTORAL WORKS AT MIT -

[12] S. Y. Hong and A. T. Radosevich*, Chemoselective Primary Amination of Aryl Boronic Acids by PIII/PV=O Catalysis: Synthetic Capture of the Transient Nef Intermediate HNO, J. Am. Chem. Soc., 2022, 144, 8902–8907.

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[11] G. Li, Y. Kanda, S. Y. Hong, and A. T. Radosevich*, Enabling Reductive C–N Cross-Coupling of Nitroalkanes and Boronic Acids by Steric Design of P(III)/P(V)=O Catalysts, J. Am. Chem. Soc., 2022, 144, 8242–8248.

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[10] Y. Kanda,† S. Y. Hong,† and A.T. Radosevich*, Selective C–H Fluoroalkylation of Azines Enabled by Tailored Phosphorus-Based Reagents, Chem, 2021, 7, 1420–1422. (†Equally contributed) – Invited Preview Article

                                                              - GRADUATED WORKS AT KAIST-

[9] S. Y. Hong, Y. Hwang, M. Lee and S. Chang*, Mechanism-Guided Development of Transition-Metal Catalyzed C–N Bond-Forming Reactions Using Dioxazolones as the Versatile Amidating Source, Acc. Chem. Res., 2021, 54, 2683–2700.


[8] S. Kim, D. Kim, S. Y. Hong* and S. Chang*, Tuning Orbital Symmetry of Iridium Nitrenoid Enables Catalytic Diastereoand Enantioselective Alkene Difunctionalizations, J. Am. Chem. Soc., 2021, 143, 10, 3993–4004. (*Co-corresponding authors)

  •  Highlighted in Organic Chemistry Portal.


[7] S. Y. Hong, D. Kim and S. Chang*, Catalytic Access to Carbocation Intermediates via Nitrenoid Transfer Leading to Allylic Lactams, Nat. Catal., 2021, 4, 79−88. 

  •  Highlighted in IBS.


[6] S. Y. Hong and S. Chang* Stereodefined Access to Lactams via Olefin Difunctionalization: Iridium Nitrenoids as a Motif of LUMO-Controlled Dipoles, J. Am. Chem. Soc., 2019, 141, 10399−10408.
  • Highlighted in Synfacts 2019, 15, 1026.


[5] S. Huh,† S. Y. Hong,† and S. Chang* Synthetic Utility of N-Benzoyloxyamides as an Alternative Precursor of Acylnitrenoids for γ-Lactam Formation, Org. Lett., 2019, 21, 2808–2812. (†Equally contributed)
  • Highlighted in Organic Chemistry Portal.

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[4] S. Y. Hong, J. Son, D. Kim, and S. Chang*; Ir(III)-Catalyzed Stereoselective Haloamidation of Alkynes Enabled by Ligand Participation, J. Am. Chem. Soc., 2018, 140, 12359-12363.
  • Highlighted in Synfacts 2018, 14, 1269.


[3] S. Y. Hong,† Y. Park,† Y. Hwang, Y. Kim, M.-H. Baik,* and S. Chang* Selective formation of γ-lactams via C–H amidation enabled by tailored iridium catalysts, Science, 2018, 359, 1016-1021. (†Equally contributed)

  • Highlighted in Nature, March 2018 / Science Daily, March 2018/Phys.Org, March 2018 / Asian Scientist, March 2018/Synfacts 2018, 14, 0464


[2] S. Y. Hong, J. Jeong, and S. Chang*; [4+2] or [4+1] Annulation: Changing the Reaction Pathway of a Rhodium-Catalyzed Process by Tuning the Cp Ligand, Angew. Chem. Int. Ed., 2017, 56, 2408–2412.


[1] S. Y. Hong,† J. Kwak,† and S. Chang*; Rhodium-Catalyzed Selective C–H Functionalization of NNN Tridentate Chelating Compounds via a Rollover Pathway, Chem. Commun. 2016, 52, 3159-3162. (†Equally contributed)

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